The Hamilton–Jacobi–Bellman (HJB) equation serves as the necessary and sufficient condition for the optimal solution to the continuous-time (CT) optimal control problem (OCP). Compared with the infinite-horizon HJB equation, the solving of the finite-horizon (FH) HJB equation has been a long-standing challenge, because the partial time derivative of the value function is involved as an additional unknown term. To address this problem, this study first-time bridges the link between the partial time derivative and the terminal-time utility function, and thus it facilitates the use of the policy iteration (PI) technique to solve the CT FH OCPs. Based on this key finding, the FH approximate dynamic programming (ADP) algorithm is proposed leveraging an actor–critic framework. It is shown that the algorithm exhibits important properties in terms of convergence and optimality. Rather importantly, with the use of multilayer neural networks (NNs) in the actor–critic architecture, the algorithm is suitable for CT FH OCPs toward more general nonlinear and complex systems. Finally, the effectiveness of the proposed algorithm is demonstrated by conducting a series of simulations on both a linear quadratic regulator (LQR) problem and a nonlinear vehicle tracking problem.